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Figure 5.4. Plot of the CWC versus lnC, where C is the initial PPAPE concentration in THF solution. Inset: scattering light intensity as a function of the water content (vol%) in the THF H2O dispersion media. The initial concentration of PPAPE in THF is 1.0 mg/mL. Source: From Li et al., 2006a.

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the logarithm of polymer concentration increases (Fig 54) Such relationship is similar to those observed for amphiphilic block copolymers (Zhang et al, 1997) When the initial concentration increases from 005 to 10 mg/mL, CWC decreases from 304% (vol%) to 252% (vol%) The size of the colloidal spheres is also closely related to the initial concentration of the polymers, which increases as the initial concentration increases By changing the initial concentration in the range aforementioned, the average size of the colloids can be adjusted from 80 to 180 nm The water content in the medium plays a key role to control the colloid formation The in uence of the water content can be studied by using dynamic light scattering (DLS) and UV-vis spectroscopy DLS indicates that when the water content increases above CWC, the hydrodynamic radius (Rh) gradually increases as the water content increases.

It s all about how much space you want to free up for listings of content, activity, and things like that Is there, for example, any real reason to show your blogroll all the time Why not put all links in one tabbed box, having a tab for your social Web profiles, another for friends Web sites, and so on That takes a lot less space, and anyone looking to delve deeper into your online presence or the friends and partners of a site is certainly not averse to using a tabbed box The same user would also most likely appreciate the tabbed box whenever it isn t the focus of attention, since it save space and makes your site a lot easier to deal with Overall, you should be careful with tabbed boxes, and the same goes for tabbed menus.

When the water content is above a certain value, Rh starts to decrease as the water content further increases and then stabilizes at the nal value The structure evolution in the process can be better understood from the UV-vis spectroscopic investigation It is well known that the photoisomerization rate and isomerization degree at the photostationary state are related to the free volume surrounding the azo chromophores (Kumar and Neckers, 1989) For azobenzene-type molecules, the isomerization behavior can be monitored by UV-vis spectroscopy and used as a molecular probe to detect the environmental variation in the systems Figure 55 shows a typical result obtained for the solutions or suspensions of PEAPE in THF-H2O media with different water contents.

It is one extra click, and that can be annoying for the visitor That being said, it s not so nice to clutter a site with lists and functions that are rarely used either, so it is all a matter of purpose and usability..

The results were obtained by irradiating the solutions of the polymer or the suspensions of the colloidal spheres with 365-nm UV light for different time intervals and recording the UV-vis spectra of the samples at each moment Upon the UV light irradiation,.

Originally published in B-to-B Online (www.btobonline.com) June 9, 2008. Reproduced with permission from VisionEdge Marketing.

Water content 23.1% 28.6% 33.3% 50.0% 80.0%

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